RR
Reshma R. Rao
cond-mat.mtrl-scioperando spectroscopyatomic-scale redoxbenchmark catalystscatalysiscond-mat.str-elcrystal phase engineeringelectrocatalysiselectrocatalystselectrode−electrolyte interface
On Valency
published · living versionsW_fbt2d27a·v1 · currentpublished
An In Situ Surface-Enhanced Infrared Absorption Spectroscopy Study of Electrochemical CO2 Reduction: Selectivity Dependence on Surface C-Bound and O-Bound Reaction Intermediates
with Yu Katayama, Francesco Nattino, Livia Giordano, Jonathan Hwang +3
1 version
Preprints & journals
35 papers in the corpus · 2017–2026Optically Tracked Reversible Single-Atomic-Monolayer Redox in Plasmonic Nanocavities.42917360 · Goerlitzer, Eric S A, Wu, Zijia, Crookes, Angus et al.2026 · 0 citationsNano letters. 2026;26(39):13272-13278
Resolving Water-Oxidation Kinetics by Combining Operando Spectroscopy with O2 Evolution Rates over Seven Orders of Magnitude10.26434/chemrxiv.15009952/v1 · Caiwu Liang, Jack Kirk Pedersen, Reshma Rao et al.2026 · 0 citationsChemRxiv
Unifying Water Oxidation Chemistry of Iridium Oxide from Aqueous Model Systems to Proton Exchange Membrane Electrolysers10.26434/chemrxiv.15008370/v1 · Caiwu Liang, James Murawski, Cindy Tseng et al.2026 · 0 citationsChemRxiv
Active Phase of Nickel Electrocatalysts Driving Alkaline Hydrogen Evolution.42590858 · Wang, Yifeng, Ender, Eleanor, Kumar, Santosh et al.2026 · 1 citationAdvanced materials (Deerfield Beach, Fla.). 2026;38(57):e74591
Cobalt cations in layered manganese dioxide tailor redox dynamics and oxygen evolution kinetics10.26434/chemrxiv.15006889/v1 · Sid Halder, Qing Su, Yifeng Wang et al.2026 · 0 citationsChemRxiv
Mechanistic Study of Glycerol Electro-Oxidation on Ni(OH)2/NiOOH Electrodes.41945599 · Yu, Youli, Wang, Yifeng, Ye, Hanzhi et al.2026 · 12 citationsJournal of the American Chemical Society. 2026;148(15):16119-16128
Spectroelectrochemical Studies of Oxygen Evolution Reaction Kinetics for Surface-Incorporated Iron in Nickel Oxyhydroxide Electrocatalysts.41953214 · Wang, Yifeng, Twight, Liam P, Sagui, Nicole A et al.2026 · 4 citationsACS catalysis. 2026;16(7):6749-6757
Multimodal Operando Characterization of Cation Effects at the Iridium Oxide-Electrolyte Interface for Alkaline Water Oxidation.41777068 · Tao, Yemin, Utsunomiya, Tomohiko, Yu, Haiting et al.2026 · 1 citationACS applied materials & interfaces. 2026;18(10):15699-15710
Key role of oxidizing species driving water oxidation revealed by time-resolved optical and X-ray spectroscopies.41748930 · Liang, Caiwu, Garcia Verga, Lucas, Moss, Benjamin et al.2026 · 13 citationsNature materials. 2026;25(5):799-807
Transient Au-Cl adlayers modulate the surface chemistry of gold nanoparticles during redox reactions.41233525 · Sibug-Torres, Sarah May, Niihori, Marika, Wyatt, Elle et al.2026 · 16 citationsNature chemistry. 2026;18(2):294-301
Multimodal Operando Characterisation of Iridium Oxide-electrolyte Interface for Water Oxidation10.26434/chemrxiv-2025-9svrk · Yemin Tao, Tomohiko Utsunomiya, Haiting Yu et al.2025 · 0 citationsChemRxiv
Crystal-Phase Engineering of Nanowires and Platelets of K x IrO2 for Efficient Water Oxidation.41245576 · Quintin-Baxendale, Rachael, Sokolikova, Maria, Tao, Yemin et al.2025 · 1 citationACS materials Au. 2025;5(6):1070-1079
Investigating Ti-Nb alloys as supports for iridium oxide water oxidation electrocatalysts10.26434/chemrxiv-2025-p15vj · Guangmeimei Yang, Wei Huang, Yifeng Wang et al.2025 · 0 citationsChemRxiv
Confined Water for Catalysis: Thermodynamic Properties and Reaction Kinetics.39902648 · Wang, Tao, Iriawan, Haldrian, Peng, Jiayu et al.2025 · 94 citationsChemical reviews. 2025;125(3):1420-1467
A hydrogen radical pathway for efficacious electrochemical nitrate reduction to ammonia over an Fe-polyoxometalate/Cu electrocatalyst.38884595 · Lee, Heebin, Kim, Keon-Han, Rao, Reshma R et al.2024 · 11 citationsMaterials horizons. 2024;11(17):4115-4122
Unraveling the Role of Particle Size and Nanostructuring on the Oxygen Evolution Activity of Fe-Doped NiO.39114087 · Rao, Reshma R, Bucci, Alberto, Corby, Sacha et al.2024 · 21 citationsACS catalysis. 2024;14(15):11389-11399
Facet-Dependent Oxygen Evolution Reaction Activity of IrO2 from Quantum Mechanics and Experiments.38636103 · Kwon, Soonho, Stoerzinger, Kelsey A, Rao, Reshma et al.2024 · 70 citationsJournal of the American Chemical Society. 2024;146(17):11719-11725
Unravelling the role of particle size and nanostructuring on the oxygen evolution activity of Fe-doped NiO10.26434/chemrxiv-2024-69059 · Reshma Rao, Alberto Bucci, Sacha Corby et al.2024 · 1 citationChemRxiv
Role of Electrolyte pH on Water Oxidation for Iridium Oxides.38526298 · Liang, Caiwu, Katayama, Yu, Tao, Yemin et al.2024 · 126 citationsJournal of the American Chemical Society. 2024;146(13):8928-8938
Cooperative Effects Drive Water Oxidation Catalysis in Cobalt Electrocatalysts through the Destabilization of Intermediates.38517290 · Moss, Benjamin, Svane, Katrine Louise, Nieto-Castro, David et al.2024 · 33 citationsJournal of the American Chemical Society. 2024;146(13):8915-8927
Extensive photochemical restructuring of molecule-metal surfaces under room light.38431651 · Guo, Chenyang, Benzie, Philip, Hu, Shu et al.2024 · 8 citationsNature communications. 2024;15(1):1928
Operando X-ray characterization of interfacial charge transfer and structural rearrangements2212.04961v1 · Reshma R. Rao, Iris C. G. van den Bosch, Christoph Baeumer2022 · 3 citationsEditors: K. Wandelt and G.o Bussetti, Encyclopedia of Solid-Liquid Interfaces, Elsevier INC, 2023, ISBN 9780323856690
Role of Ni in PtNi Bimetallic Electrocatalysts for Hydrogen and Value-Added Chemicals Coproduction via Glycerol Electrooxidation.36504912 · Luo, Hui, Yukuhiro, Victor Y, Fernández, Pablo S et al.2022 · 85 citationsACS catalysis. 2022;12(23):14492-14506
Spectroelectrochemistry of Water Oxidation Kinetics in Molecular versus Heterogeneous Oxide Iridium Electrocatalysts.35511107 · Bozal-Ginesta, Carlota, Rao, Reshma R, Mesa, Camilo A et al.2022 · 53 citationsJournal of the American Chemical Society. 2022;144(19):8454-8459
Spectroelectrochemical Analysis of the Water Oxidation Mechanism on Doped Nickel Oxides.35442661 · Rao, Reshma R, Corby, Sacha, Bucci, Alberto et al.2026 · 238 citationsJournal of the American Chemical Society. 2022;144(17):7622-7633
The low overpotential regime of acidic water oxidation part II: trends in metal and oxygen stability numbers.35706421 · Scott, Soren B, Sørensen, Jakob E, Rao, Reshma R et al.2024 · 89 citationsEnergy & environmental science. 2022;15(5):1988-2001
The low overpotential regime of acidic water oxidation part I: the importance of O2 detection.35706423 · Scott, Soren B, Rao, Reshma R, Moon, Choongman et al.2022 · 68 citationsEnergy & environmental science. 2022;15(5):1977-1987
Cation- and pH-Dependent Hydrogen Evolution and Oxidation Reaction Kinetics.34723270 · Huang, Botao, Rao, Reshma R, You, Sifan et al.2021 · 374 citationsJACS Au. 2021;1(10):1674-1687
Operando spectroelectrochemistry of redox state kinetics in water-oxidation IrOx electrocatalysts10.26434/chemrxiv-2021-2sph0 · Carlota Bozal-Ginesta, Reshma R. Rao, Camilo A. Mesa et al.2021 · 0 citationsChemRxiv
Reply to: Questioning the rate law in the analysis of water oxidation catalysis on haematite photoanodes.33168963 · Mesa, Camilo A, Rao, Reshma R, Francàs, Laia et al.2026 · 19 citationsNature chemistry. 2020;12(12):1099-1101
Stern Layers on Surfaces of RuO2(100), RuO2(110), and Pt(111): Surface X-ray Scattering Studies2002.11521v1 · Tomoya Kawaguchi, Reshma R. Rao, Jaclyn R. Lunger et al.2020 · 0 citationsarXiv
An In Situ Surface-Enhanced Infrared Absorption Spectroscopy Study of Electrochemical CO2 Reduction: Selectivity Dependence on Surface C-Bound and O-Bound Reaction Intermediates1904.11299v1 · Yu Katayama, Francesco Nattino, Livia Giordano et al.2019 · 329 citationsJ. Phys. Chem. C 123, 5951 (2019)on Valency
Recommended Practices and Benchmark Activity for Hydrogen and Oxygen Electrocatalysis in Water Splitting and Fuel Cells.30656754 · Wei, Chao, Rao, Reshma R, Peng, Jiayu et al.2020 · 1,368 citationsAdvanced materials (Deerfield Beach, Fla.). 2019;31(31):e1806296
Anomalous Antiferromagnetism in Metallic RuO_2 Determined by Resonant X-ray Scattering.31012682 · Zhu, Z H, Strempfer, J, Rao, R R et al.2019 · 210 citationsPhysical review letters. 2019;122(1):017202
Perovskites in catalysis and electrocatalysis.29123062 · Hwang, Jonathan, Rao, Reshma R, Giordano, Livia et al.2018 · 1,802 citationsScience (New York, N.Y.). 2017;358(6364):751-756
Career total: at least 118 works. 35 are in this corpus.
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