AM
Arimasa Matsumoto
asymmetric amplificationautocatalysisasymmetric catalysischiralityhomochirality5-pyrimidyl alkanolasymmetric autocatalysisenantioselectivitySoai reaction[2.2]paracyclophane
On Valency
published · living versionsW_2ajarcrs·v1 · currentpublished
Role of Asymmetric Autocatalysis in the Elucidation of Origins of Homochirality of Organic Compounds
with Kenso Soai, Tsuneomi Kawasaki
1 version
W_9yg969x5·v1published
W_kyxnht6w·v1published
W_f6w2p2ta·v1published
Preprints & journals
37 papers in the corpus · 2008–2026Accessing an Extreme Steric Regime of C–O Atropisomerism through Overcrowded Iodane-Mediated Rearrangement10.26434/chemrxiv.15009250/v1 · Bin Li, Jun Kikuchi, Arimasa Matsumoto et al.2026 · 0 citationsChemRxiv
"T-Shaped" Excimer Fluorescence of Chiral Crystals of [2.2]Paracyclophane-Containing Organoboron Complexes.41865252 · Irii, Shun, Ogaki, Takuya, Matsumoto, Arimasa et al.2026 · 1 citationChemistry, an Asian journal. 2026;21(6):e70693
Carbon-iodine atropisomerism on triazole and triazolium frameworks: a breathing axle with divergent adaptivity.41635912 · Nambu, Ryoga, Kikuchi, Jun, Matsumoto, Arimasa et al.2026 · 2 citationsChemical science. 2026;17(12):6109-6115
Stable and responsive atropisomerism around a carbon–iodine bond10.26434/chemrxiv-2024-t16qt · Naohiko Yoshikai, Shohei Abe, Jun Kikuchi et al.2024 · 0 citationsChemRxiv
Stereoselective Hydroxyallylation of Cyclopropenes with Cyclopropanols via NHC Catalysis of Transient Organozinc Species.39107239 · Tsukiji, Kento, Matsumoto, Arimasa, Kanemoto, Kazuya et al.2024 · 14 citationsAngewandte Chemie (International ed. in English). 2024;63(46):e202412456
Achiral 2-pyridone and 4-aminopyridine act as chiral inducers of asymmetric autocatalysis with amplification of enantiomeric excess via the formation of chiral crystals.37621025 · Matsumoto, Arimasa, Tateishi, Daisuke, Nakajima, Tsuyoshi et al.2023 · 4 citationsChirality. 2024;36(1):e23617
Asymmetric Autocatalysis as an Efficient Link Between the Origin of Homochirality and Highly Enantioenriched Compounds.35960427 · Soai, Kenso, Kawasaki, Tsuneomi, Matsumoto, Arimasa2022 · 9 citationsOrigins of life and evolution of the biosphere : the journal of the International Society for the Study of the Origin of Life. 2022;52(1-3):57-74
Chiral Dinuclear EuIII , TbIII , and YIII Complexes Supported by P-Stereogenic Linear Tetraphosphine Tetraoxide.34911149 · Tanase, Tomoaki, Nakamae, Kanako, Okawa, Yume et al.2022 · 9 citationsChemistry (Weinheim an der Bergstrasse, Germany). 2022;28(8):e202104060
A Synthetic Model for the Possible FeIV2(μ-O)2 Core of Methane Monooxygenase Intermediate Q Derived from a Structurally Characterized FeIIIFeIV(μ-O)2 Complex.34822245 · Mikata, Yuji, Aono, Yuri, Yamamoto, Chihiro et al.2024 · 5 citationsInorganic chemistry. 2022;61(2):786-790
Circular dichroism spectroscopy of catalyst preequilibrium in asymmetric autocatalysis of pyrimidyl alkanol.34622895 · Matsumoto, Arimasa, Tanaka, Ayame, Kaimori, Yoshiyasu et al.2021 · 10 citationsChemical communications (Cambridge, England). 2021;57(85):11209-11212
Asymmetric autocatalysis triggered by triglycine sulfate with switchable chirality by altering the direction of the applied electric field.34023863 · Kawasaki, Tsuneomi, Kaimori, Yoshiyasu, Shimada, Seiya et al.2021 · 14 citationsChemical communications (Cambridge, England). 2021;57(49):5999-6002
Structure and electrochemical properties of (μ-O)2Mn2(iii,iii) and (μ-O)2Mn2(iii,iv) complexes supported by pyridine-, quinoline-, isoquinoline- and quinoxaline-based tetranitrogen ligands.33729253 · Mikata, Yuji, Kuroda, Yasuko, Naito, Kyoko et al.2021 · 11 citationsDalton transactions (Cambridge, England : 2003). 2021;50(12):4133-4144
Chiral approach to investigate mechanism of highly efficient thermally activated delayed fluorescence.33544108 · Hayashi, Kikuya, Matsumoto, Arimasa, Hirata, Shuzo2021 · 6 citationsChemical communications (Cambridge, England). 2021;57(14):1738-1741
Switching of Fluorescent Zn/Cd Selectivity in N,N,N',N'-Tetrakis(6-methoxy-2-quinolylmethyl)-1,2-diphenylethylenediamine by One Asymmetric Carbon Atom Inversion.32048842 · Mikata, Yuji, Nozaki, Kana, Tanaka, Marin et al.2020 · 15 citationsInorganic chemistry. 2020;59(8):5313-5324
Achiral amino acid glycine acts as an origin of homochirality in asymmetric autocatalysis.30932119 · Matsumoto, Arimasa, Ozaki, Hanae, Tsuchiya, Sumeru et al.2019 · 27 citationsOrganic & biomolecular chemistry. 2019;17(17):4200-4203
Formation of enantioenriched alkanol with stochastic distribution of enantiomers in the absolute asymmetric synthesis under heterogeneous solid-vapor phase conditions.30968100 · Kaimori, Yoshiyasu, Hiyoshi, Yui, Kawasaki, Tsuneomi et al.2019 · 28 citationsChemical communications (Cambridge, England). 2019;55(36):5223-5226
Methoxy-substituted tetrakisquinoline analogs of EGTA and BAPTA for fluorescence detection of Cd2+ .30698189 · Mikata, Yuji, Kaneda, Minori, Konno, Hideo et al.2019 · 14 citationsDalton transactions (Cambridge, England : 2003). 2019;48(12):3840-3852
Pyrophosphate-Induced Intramolecular Excimer Formation in Dinuclear Zinc(II) Complexes with Tetrakisquinoline Ligands.29905465 · Mikata, Yuji, Ohnishi, Risa, Nishijima, Risa et al.2018 · 17 citationsInorganic chemistry. 2018;57(13):7724-7734
Reversal of the sense of enantioselectivity between 1- and 2-aza[6]helicenes used as chiral inducers of asymmetric autocatalysis.28102409 · Matsumoto, Arimasa, Yonemitsu, Kento, Ozaki, Hanae et al.2018 · 45 citationsOrganic & biomolecular chemistry. 2017;15(6):1321-1324
Can the analyte-triggered asymmetric autocatalytic Soai reaction serve as a universal analytical tool for measuring enantiopurity and assigning absolute configuration?27714244 · Welch, Christopher J, Zawatzky, Kerstin, Makarov, Alexey A et al.2018 · 11 citationsOrganic & biomolecular chemistry. 2016;15(1):96-101
Achiral Inorganic Gypsum Acts as an Origin of Chirality through Its Enantiotopic Surface in Conjunction with Asymmetric Autocatalysis.27906493 · Matsumoto, Arimasa, Kaimori, Yoshiyasu, Uchida, Mizuki et al.2018 · 46 citationsAngewandte Chemie (International ed. in English). 2017;56(2):545-548
Point-to-Point Ultra-Remote Asymmetric Control with Flexible Linker.27801951 · Kawasaki, Tsuneomi, Ishikawa, Yasuyuki, Minato, Yoshihiro et al.2017 · 10 citationsChemistry (Weinheim an der Bergstrasse, Germany). 2017;23(2):282-285
Asymmetric Induction by a Nitrogen 14 N/15 N Isotopomer in Conjunction with Asymmetric Autocatalysis.27754589 · Matsumoto, Arimasa, Ozaki, Hanae, Harada, Shunya et al.2018 · 53 citationsAngewandte Chemie (International ed. in English). 2016;55(49):15246-15249
Crystal Structure of the Isopropylzinc Alkoxide of Pyrimidyl Alkanol: Mechanistic Insights for Asymmetric Autocatalysis with Amplification of Enantiomeric Excess.26494200 · Matsumoto, Arimasa, Abe, Takaaki, Hara, Atsushi et al.2016 · 75 citationsAngewandte Chemie (International ed. in English). 2015;54(50):15218-21
Helical mesoporous silica as an inorganic heterogeneous chiral trigger for asymmetric autocatalysis with amplification of enantiomeric excess.25803308 · Kawasaki, Tsuneomi, Araki, Yuko, Hatase, Kunihiko et al.2016 · 65 citationsChemical communications (Cambridge, England). 2015;51(42):8742-4on Valency
Asymmetric autocatalysis of pyrimidyl alkanol and its application to the study on the origin of homochirality.25511374 · Soai, Kenso, Kawasaki, Tsuneomi, Matsumoto, Arimasa2015 · 181 citationsAccounts of chemical research. 2014;47(12):3643-54
Self-replication and amplification of enantiomeric excess of chiral multifunctionalized large molecules by asymmetric autocatalysis.25195925 · Kawasaki, Tsuneomi, Nakaoda, Mai, Takahashi, Yutaro et al.2015 · 32 citationsAngewandte Chemie (International ed. in English). 2014;53(42):11199-202
The origins of homochirality examined by using asymmetric autocatalysis.24449510 · Soai, Kenso, Kawasaki, Tsuneomi, Matsumoto, Arimasa2014 · 89 citationsChemical record (New York, N.Y.). 2014;14(1):70-83
Asymmetric autocatalysis initiated by finite single-wall carbon nanotube molecules with helical chirality.24417337 · Hitosugi, Shunpei, Matsumoto, Arimasa, Kaimori, Yoshiyasu et al.2014 · 33 citationsOrganic letters. 2014;16(3):645-7
Asymmetric autocatalysis induced by cinnabar: observation of the enantioselective adsorption of a 5-pyrimidyl alkanol on the crystal surface.23881646 · Shindo, Hitoshi, Shirota, Yusuke, Niki, Kaori et al.2014 · 59 citationsAngewandte Chemie (International ed. in English). 2013;52(35):9135-8
Asymmetric autocatalysis triggered by oxygen isotopically chiral glycerin.23487262 · Matsumoto, Arimasa, Oji, Shotaro, Takano, Shizuka et al.2013 · 45 citationsOrganic & biomolecular chemistry. 2013;11(18):2928-31
β-Arylation of carboxamides via iron-catalyzed C(sp3)-H bond activation.23581730 · Shang, Rui, Ilies, Laurean, Matsumoto, Arimasa et al.2013 · 275 citationsJournal of the American Chemical Society. 2013;135(16):6030-2
Asymmetric autocatalysis initiated by achiral nucleic acid base adenine: implications on the origin of homochirality of biomolecules.22992576 · Mineki, Hiroko, Hanasaki, Taichi, Matsumoto, Arimasa et al.2013 · 42 citationsChemical communications (Cambridge, England). 2012;48(85):10538-40
Phenanthrene synthesis by iron-catalyzed [4+2] benzannulation between alkyne and biaryl or 2-alkenylphenyl Grignard reagent.21473580 · Matsumoto, Arimasa, Ilies, Laurean, Nakamura, Eiichi2011 · 180 citationsJournal of the American Chemical Society. 2011;133(17):6557-9
Iron-catalyzed C-C bond formation at alpha-position of aliphatic amines via C-H bond activation through 1,5-hydrogen transfer.20361736 · Yoshikai, Naohiko, Mieczkowski, Adam, Matsumoto, Arimasa et al.2010 · 180 citationsJournal of the American Chemical Society. 2010;132(16):5568-9
Iron-catalyzed chemoselective ortho arylation of aryl imines by directed C-H bond activation.19294714 · Yoshikai, Naohiko, Matsumoto, Arimasa, Norinder, Jakob et al.2009 · 237 citationsAngewandte Chemie (International ed. in English). 2009;48(16):2925-8
Iron-catalyzed direct arylation through directed C-H bond activation.18410099 · Norinder, Jakob, Matsumoto, Arimasa, Yoshikai, Naohiko et al.2008 · 401 citationsJournal of the American Chemical Society. 2008;130(18):5858-9
Career total: 181 works. 37 are in this corpus.
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