TK
Tsuneomi Kawasaki
asymmetric amplificationautocatalysischiralityasymmetric catalysisenantioselectivityhomochirality5-pyrimidyl alkanolamino acidsAmino Acidsasymmetric autocatalysis
On Valency
published · living versionsW_2ajarcrs·v1 · currentpublished
Role of Asymmetric Autocatalysis in the Elucidation of Origins of Homochirality of Organic Compounds
with Kenso Soai, Arimasa Matsumoto
1 version
W_kyxnht6w·v1published
Preprints & journals
56 papers in the corpus · 2005–2026Replication of chiral α-hydroxy acids via induction and amplification through an enantioenriched cyanohydrin conglomerate.42359747 · Kawasaki, Tsuneomi, Takamatsu, Naoya, Aiba, Shohei et al.2026 · 0 citationsOrganic & biomolecular chemistry. 2026;24(29):6005-6011
Synthesis of enantioenriched aminonitriles catalysed by cyanohydrins and hydroxy acids: propagation of chirality in Strecker-type synthesis10.26434/chemrxiv.15002264/v1 · Kohei Niikura, Ryota Kobayashi, Masaki Kato et al.2026 · 0 citationsChemRxiv
Achiral 2-pyridone and 4-aminopyridine act as chiral inducers of asymmetric autocatalysis with amplification of enantiomeric excess via the formation of chiral crystals.37621025 · Matsumoto, Arimasa, Tateishi, Daisuke, Nakajima, Tsuyoshi et al.2023 · 4 citationsChirality. 2024;36(1):e23617
Chirally and chemically reversible Strecker reaction.37152252 · Machida, Yutaro, Tanaka, Yudai, Masuda, Yuya et al.2023 · 13 citationsChemical science. 2023;14(17):4480-4484
Asymmetric Strecker reaction at the solid/solid interface.36408703 · Yoshimura, Yuki, Tanaka, Yudai, Kobayashi, Ryota et al.2023 · 2 citationsOrganic & biomolecular chemistry. 2023;21(3):520-524
Asymmetric Autocatalysis as an Efficient Link Between the Origin of Homochirality and Highly Enantioenriched Compounds.35960427 · Soai, Kenso, Kawasaki, Tsuneomi, Matsumoto, Arimasa2022 · 9 citationsOrigins of life and evolution of the biosphere : the journal of the International Society for the Study of the Origin of Life. 2022;52(1-3):57-74
Quantitative Difference in Solubility of Diastereomeric (2H/1H)-Isotopomers.34738466 · Kawasaki, Tsuneomi, Kubo, Hiroki, Nishiyama, Satoshi et al.2022 · 6 citationsJournal of the American Chemical Society. 2021;143(46):19525-19531
Asymmetric autocatalysis triggered by triglycine sulfate with switchable chirality by altering the direction of the applied electric field.34023863 · Kawasaki, Tsuneomi, Kaimori, Yoshiyasu, Shimada, Seiya et al.2021 · 14 citationsChemical communications (Cambridge, England). 2021;57(49):5999-6002
Utilization of a Crown Ether/Amine-Type Rotaxane as a Probe for the Versatile Detection of Anions and Acids by Thin-Layer Chromatography.32783335 · Miyagawa, Shinobu, Kimura, Masaki, Kagami, Shin et al.2020 · 6 citationsChemistry, an Asian journal. 2020;15(19):3044-3049
Investigation on the Epoxidation of Piperitenone, and Structure-activity Relationships of Piperitenone Oxide for Differentiation-inducing Activity.32641605 · Sato, Ryohei, Sasaki, Azusa, Mori, Yuko et al.2020 · 1 citationJournal of oleo science. 2020;69(8):951-958
Achiral amino acid glycine acts as an origin of homochirality in asymmetric autocatalysis.30932119 · Matsumoto, Arimasa, Ozaki, Hanae, Tsuchiya, Sumeru et al.2019 · 27 citationsOrganic & biomolecular chemistry. 2019;17(17):4200-4203
Formation of enantioenriched alkanol with stochastic distribution of enantiomers in the absolute asymmetric synthesis under heterogeneous solid-vapor phase conditions.30968100 · Kaimori, Yoshiyasu, Hiyoshi, Yui, Kawasaki, Tsuneomi et al.2019 · 28 citationsChemical communications (Cambridge, England). 2019;55(36):5223-5226
Synthesis, antibacterial and cytotoxic evaluation of flavipucine and its derivatives.30935798 · Kusakabe, Yasuha, Mizutani, Shoma, Kamo, Shogo et al.2020 · 18 citationsBioorganic & medicinal chemistry letters. 2019;29(11):1390-1394
Absolute asymmetric Strecker synthesis in a mixed aqueous medium: reliable access to enantioenriched α-aminonitrile.30656321 · Miyagawa, Shinobu, Aiba, Shohei, Kawamoto, Hajime et al.2019 · 12 citationsOrganic & biomolecular chemistry. 2019;17(5):1238-1244
Synthesis of a Chiral [2]Rotaxane: Induction of a Helical Structure through Double Threading.30058808 · Tsukamoto, Toshihiro, Sasahara, Ryota, Muranaka, Atsuya et al.2018 · 13 citationsOrganic letters. 2018;20(16):4745-4748
Formation of [2]- and [3]Rotaxanes through Bridging under Kinetic and Thermodynamic Control.29283267 · Fujino, Takaaki, Naitoh, Hirotake, Miyagawa, Shinobu et al.2018 · 13 citationsOrganic letters. 2018;20(2):369-372
Highly Stereoselective Strecker Synthesis Induced by a Slight Modification of Benzhydrylamine from Achiral to Chiral.28980348 · Takamatsu, Naoya, Aiba, Shohei, Yamada, Takuya et al.2018 · 15 citationsChemistry (Weinheim an der Bergstrasse, Germany). 2018;24(6):1304-1310
Four-State Molecular Shuttling of [2]Rotaxanes in Response to Acid/Base and Alkali-Metal Cation Stimuli.28409890 · Kimura, Masaki, Mizuno, Takuma, Ueda, Masahiro et al.2018 · 10 citationsChemistry, an Asian journal. 2017;12(12):1381-1390
Asymmetric Strecker Reaction Arising from the Molecular Orientation of an Achiral Imine at the Single-Crystal Face: Enantioenriched l- and d-Amino Acids.28004489 · Miyagawa, Shinobu, Yoshimura, Koji, Yamazaki, Yusuke et al.2018 · 37 citationsAngewandte Chemie (International ed. in English). 2017;56(4):1055-1058
Achiral Inorganic Gypsum Acts as an Origin of Chirality through Its Enantiotopic Surface in Conjunction with Asymmetric Autocatalysis.27906493 · Matsumoto, Arimasa, Kaimori, Yoshiyasu, Uchida, Mizuki et al.2018 · 46 citationsAngewandte Chemie (International ed. in English). 2017;56(2):545-548
Point-to-Point Ultra-Remote Asymmetric Control with Flexible Linker.27801951 · Kawasaki, Tsuneomi, Ishikawa, Yasuyuki, Minato, Yoshihiro et al.2017 · 10 citationsChemistry (Weinheim an der Bergstrasse, Germany). 2017;23(2):282-285
Asymmetric Induction by a Nitrogen 14 N/15 N Isotopomer in Conjunction with Asymmetric Autocatalysis.27754589 · Matsumoto, Arimasa, Ozaki, Hanae, Harada, Shunya et al.2018 · 53 citationsAngewandte Chemie (International ed. in English). 2016;55(49):15246-15249
Replication of α-amino acids via Strecker synthesis with amplification and multiplication of chiral intermediate aminonitriles.27492553 · Aiba, Shohei, Takamatsu, Naoya, Sasai, Taichiro et al.2018 · 28 citationsChemical communications (Cambridge, England). 2016;52(72):10834-7
Five-State Molecular Shuttling of a Pair of [2]Rotaxanes: Distinct Outputs in Response to Acid and Base Stimuli.27355789 · Ueda, Masahiro, Terazawa, Shoya, Deguchi, Yasuaki et al.2018 · 9 citationsChemistry, an Asian journal. 2016;11(16):2291-300
Crystal Structure of the Isopropylzinc Alkoxide of Pyrimidyl Alkanol: Mechanistic Insights for Asymmetric Autocatalysis with Amplification of Enantiomeric Excess.26494200 · Matsumoto, Arimasa, Abe, Takaaki, Hara, Atsushi et al.2016 · 75 citationsAngewandte Chemie (International ed. in English). 2015;54(50):15218-21
Spontaneous formation and amplification of an enantioenriched α-amino nitrile: a chiral precursor for Strecker amino acid synthesis.26269321 · Kawasaki, Tsuneomi, Takamatsu, Naoya, Aiba, Shohei et al.2016 · 51 citationsChemical communications (Cambridge, England). 2015;51(76):14377-80
Helical mesoporous silica as an inorganic heterogeneous chiral trigger for asymmetric autocatalysis with amplification of enantiomeric excess.25803308 · Kawasaki, Tsuneomi, Araki, Yuko, Hatase, Kunihiko et al.2016 · 65 citationsChemical communications (Cambridge, England). 2015;51(42):8742-4on Valency
Asymmetric autocatalysis of pyrimidyl alkanol and its application to the study on the origin of homochirality.25511374 · Soai, Kenso, Kawasaki, Tsuneomi, Matsumoto, Arimasa2015 · 181 citationsAccounts of chemical research. 2014;47(12):3643-54
Self-replication and amplification of enantiomeric excess of chiral multifunctionalized large molecules by asymmetric autocatalysis.25195925 · Kawasaki, Tsuneomi, Nakaoda, Mai, Takahashi, Yutaro et al.2015 · 32 citationsAngewandte Chemie (International ed. in English). 2014;53(42):11199-202
The origins of homochirality examined by using asymmetric autocatalysis.24449510 · Soai, Kenso, Kawasaki, Tsuneomi, Matsumoto, Arimasa2014 · 89 citationsChemical record (New York, N.Y.). 2014;14(1):70-83
Five-state molecular switching of a [3]rotaxane in response to weak and strong acid and base stimuli.24196369 · Tokunaga, Yuji, Ikezaki, Syuji, Kimura, Masaki et al.2014 · 19 citationsChemical communications (Cambridge, England). 2013;49(100):11749-51
Asymmetric autocatalysis induced by cinnabar: observation of the enantioselective adsorption of a 5-pyrimidyl alkanol on the crystal surface.23881646 · Shindo, Hitoshi, Shirota, Yusuke, Niki, Kaori et al.2014 · 59 citationsAngewandte Chemie (International ed. in English). 2013;52(35):9135-8
Asymmetric autocatalysis triggered by oxygen isotopically chiral glycerin.23487262 · Matsumoto, Arimasa, Oji, Shotaro, Takano, Shizuka et al.2013 · 45 citationsOrganic & biomolecular chemistry. 2013;11(18):2928-31
Asymmetric autocatalysis initiated by achiral nucleic acid base adenine: implications on the origin of homochirality of biomolecules.22992576 · Mineki, Hiroko, Hanasaki, Taichi, Matsumoto, Arimasa et al.2013 · 42 citationsChemical communications (Cambridge, England). 2012;48(85):10538-40
Absolute chirality of the γ-polymorph of glycine: correlation of the absolute structure with the optical rotation.22576375 · Ishikawa, Kazuhiko, Tanaka, Masahito, Suzuki, Toshiya et al.2016 · 29 citationsChemical communications (Cambridge, England). 2012;48(48):6031-3
Asymmetric autocatalysis: triggered by chiral isotopomer arising from oxygen isotope substitution.21761523 · Kawasaki, Tsuneomi, Okano, Yasushi, Suzuki, Etsuharu et al.2013 · 78 citationsAngewandte Chemie (International ed. in English). 2011;50(35):8131-3
Enantioselective C-C bond formation as a result of the oriented prochirality of an achiral aldehyde at the single-crystal face upon treatment with a dialkyl zinc vapor.21678535 · Kawasaki, Tsuneomi, Kamimura, Sayaka, Amihara, Ai et al.2011 · 45 citationsAngewandte Chemie (International ed. in English). 2011;50(30):6796-8
Enantioselective synthesis induced by chiral crystal composed of DL-serine in conjunction with asymmetric autocatalysis.21434610 · Kawasaki, Tsuneomi, Sasagawa, Taisuke, Shiozawa, Kazuya et al.2011 · 34 citationsOrganic letters. 2011;13(9):2361-3
A reversal phenomenon of enantioface selectivity by the cooperative operation of two chiral catalysts.21431117 · Kawasaki, Tsuneomi, Wakushima, Yuki, Asahina, Mai et al.2011 · 18 citationsChemical communications (Cambridge, England). 2011;47(18):5277-9
Generation of absolute controlled crystal chirality by the removal of crystal water from achiral crystal of nucleobase cytosine.20196621 · Kawasaki, Tsuneomi, Hakoda, Yuko, Mineki, Hiroko et al.2010 · 65 citationsJournal of the American Chemical Society. 2010;132(9):2874-5
Asymmetric autocatalysis induced by chiral crystals of achiral tetraphenylethylenes.19911300 · Kawasaki, Tsuneomi, Nakaoda, Mai, Kaito, Nobuhiro et al.2010 · 50 citationsOrigins of life and evolution of the biosphere : the journal of the International Society for the Study of the Origin of Life. 2010;40(1):65-78
Discrimination of cryptochirality in chiral isotactic polystyrene by asymmetric autocatalysis.19753377 · Kawasaki, Tsuneomi, Hohberger, Christiane, Araki, Yuko et al.2009 · 41 citationsChemical communications (Cambridge, England). 2009(37):5621-3
Asymmetric autocatalysis induced by meteoritic amino acids with hydrogen isotope chirality.19597604 · Kawasaki, Tsuneomi, Shimizu, Masako, Nishiyama, Daisuke et al.2009 · 83 citationsChemical communications (Cambridge, England). 2009(29):4396-8
Asymmetric autocatalysis triggered by carbon isotope (13C/12C) chirality.19325079 · Kawasaki, Tsuneomi, Matsumura, Yukari, Tsutsumi, Takashi et al.2009 · 222 citationsScience (New York, N.Y.). 2009;324(5926):492-5
Highly enantioselective asymmetric autocatalysis using chiral ruthenium complex-ion-exchanged synthetic hectorite as a chiral initiator.19262924 · Kawasaki, Tsuneomi, Omine, Toshiki, Suzuki, Kenta et al.2009 · 22 citationsOrganic & biomolecular chemistry. 2009;7(6):1073-5
Enantioselective synthesis utilizing enantiomorphous organic crystal of achiral benzils as a source of chirality in asymmetric autocatalysis.18722453 · Kawasaki, Tsuneomi, Harada, Yuuki, Suzuki, Kenta et al.2008 · 42 citationsOrganic letters. 2008;10(18):4085-8
Mechanistic insights in the reversal of enantioselectivity of chiral catalysts by achiral catalysts in asymmetric autocatalysis.18271582 · Lutz, François, Igarashi, Takashi, Kinoshita, Tomoyuki et al.2008 · 68 citationsJournal of the American Chemical Society. 2008;130(10):2956-8
Achiral nucleobase cytosine acts as an origin of homochirality of biomolecules in conjunction with asymmetric autocatalysis.18058873 · Kawasaki, Tsuneomi, Suzuki, Kenta, Hakoda, Yuko et al.2008 · 115 citationsAngewandte Chemie (International ed. in English). 2008;47(3):496-9
Spontaneous absolute asymmetric synthesis in the presence of achiral silica gel in conjunction with asymmetric autocatalysis.16612805 · Kawasaki, Tsuneomi, Suzuki, Kenta, Shimizu, Masako et al.2007 · 110 citationsChirality. 2006;18(7):479-82
Discovery of asymmetric autocatalysis with amplification of chirality and its implication in chiral homogeneity of biomolecules.16676331 · Soai, Kenso, Kawasaki, Tsuneomi2007 · 90 citationsChirality. 2006;18(7):469-78
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