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Universal dynamics of quantum phase transitions with fractional long-range interactions

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  • Claude · Anthropic
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Abstract

The complete statistical characterization of defects generated in a quantum phase transition has mostly been studied in exactly solvable models, and remains little explored in nonintegrable systems such as long-range interacting spin chains. We characterize the full defect counting statistics in a nonintegrable long-range spin chain, the fractional Ising model, by time-dependent variational-principle simulations within the matrix-product-state and matrix-product-operator formalism. Fractional interactions capture emergent multiscale correlations and long-range effects in nature, governed by the order of the underlying fractional derivative. Such couplings can be approximated on existing quantum simulation platforms, where the full defect statistics can be measured. The defect number cumulants follow power laws in the driving time, with exponents that vary continuously with the fractional order. At low fractional order, deep in the long-range regime, the mean defect number decays more slowly than predicted by the Kibble-Zurek mechanism (KZM), while at intermediate order the KZM holds with the numerically extracted many-body critical exponents. At large fractional order, the exactly solvable free-fermion limit of the model becomes progressively more accurate towards the short-range limit. We derive exact bounds on the kink-number cumulants and on the kink-kink correlations, implying an exact Gaussian limiting distribution for large system sizes. In the many-body simulations, however, kinks are more correlated, consistent with the confinement of domain walls, and these bounds are violated in the long-range regime, also in the bulk of the chain. Nevertheless, the kink distribution still approaches a Gaussian for large defect numbers, with proportionality partially broken between the cumulants.

Introduction

In the Kibble-Zurek (KZ) mechanism, equilibrium properties determine a nonequilibrium phenomenon. The critical exponents of a continuous phase transition fix how the density of topological defects scales with the rate at which the transition is crossed [1, 2, 3, 4, 5]. The validity of the KZ mechanism in the quantum domain was theoretically established in a series of seminal works, from minimal two-level settings to genuinely many-body ones [6, 7, 8, 9]. Subsequent efforts have involved experimental tests in quantum simulators [10, 11, 12, 13, 14, 15, 16, 17, 18], which have also revealed its breakdown in frustrated lattices [19], and ultracold atomic systems [20, 21, 22, 23, 24, 25], as well as numerical simulations [26, 27], including classical benchmarks of claimed quantum advantage [28]. The universality unveiled by the KZ scaling extends to the full counting statistics of topological defects, whereby every defect number cumulant follows the same power law as the average [29, 30, 31, 32, 33, 34]. In quantum Ising chains, the defects are identical to kinks arising from spontaneous Z2\mathbb{Z}_2 symmetry breaking and separating domains of opposite magnetization. These results

assume that kinks form independently of each other. In a spin chain with fractional long-range interactions, we find that the critical exponents still fix the defect density at intermediate range, while at long range, where interactions bind defects into pairs, the variance of the kink number exceeds twice its mean, the upper limit for any free-fermion state.

Long-range interactions arise naturally on a variety of quantum simulation platforms [35], and power-law interacting systems have been experimentally investigated with trapped-ion crystals [36, 37, 38], in Rydberg quantum simulators [11], and in condensed matter [39]. In this setting, nonequilibrium scaling laws were found in a pioneering study in the Lipkin-Meshkov-Glick (LMG) model [40]. The KZ scaling holds in the exactly solvable long-range Kitaev chain, with anomalous deviations in parts of parameter space [41, 42], while in the strong long-range limit the kink density becomes independent of the driving rate [43, 44]. Matrix-product-state simulations of the long-range Ising chain found power-law scaling with exponents that change by about 25% with the interaction range [45]. The KZ scaling also persists in classical regular networks of low connectivity [46] and under truncated counterdiabatic driving [47, 48, 49]. Experimentally, trapped-ion quantum simulators have observed the KZ mechanism in the long-range transverse-field Ising model [50]. Beyond the mean number of defects, their universal statistics has been characterized in free-fermion models, including long-range Kitaev chains [32, 49, 51] in agreement with previous beyond-KZM studies [29, 30, 31], also in the presence of noise [12, 13, 51, 52]. In Rydberg chains, domain-wall statistics were measured after a single sweep [53], and the defect number distribution after slow ramps departs from that of independently formed defects [54]. In the LMG model the defect number follows a negative binomial distribution, which is super-Poissonian [44]. Despite these advances, even the average number of kinks remains poorly understood in nonintegrable long-range spin systems, while their full counting statistics has so far been obtained only for free-fermion chains and in the fully connected limit, and has not been explored in nonintegrable spin chains, especially in the most exciting long-range interacting regime. Most pressingly, it remains open whether kink-kink interactions induce a domain-wall confinement strong enough to break the independent kink formation assumed in the free-fermion description, leading to completely different counting statistics.

A prominent route to long-range quantum critical dynamics is provided by fractional calculus, which extends differentiation and integration to noninteger order and is widely used to model anomalous transport [55, 56, 57] and wave propagation in optics [58, 59, 60]. In quantum mechanics, it leads to the fractional Schrödinger equation, originally derived from Lévy-flight path integrals in which the Brownian paths of the Feynman construction are replaced by paths with heavy-tailed step-length statistics [61, 62]. The fractional order acts as a Lévy index and controls the diffusive character of the quantum states. A standard realization is the Riesz fractional derivative, defined in momentum space by ∂qf(x)→−∣k∣qf~(k)\partial_q f(x) \to-\lvert k\rvert^q \tilde{f}(k), with f~(k)\tilde{f}(k) the Fourier transform of f(x)f(x). For noninteger qq, the Riesz fractional derivative is no longer local in position space [63, 64]. Yet, Lévy flights provide a natural origin for it. For 0<q<20 < q < 2, their stable jump-length distribution, with the heavy tail ∣x∣−(1+q)\lvert x\rvert^{-(1+q)}, has the characteristic function e−∣k∣qe^{-\lvert k\rvert^q}, so that the composition of many microscopic steps accumulates a factor −∣k∣q-\lvert k\rvert^q in the exponent [62, 65]. The nonlocality is therefore inherited from the stability of the underlying jump statistics rather than imposed by hand as a prescribed algebraic decay. By the generalized central limit theorem, sums of many heavy-tailed steps approach Lévy-stable laws, just as sums of steps with finite variance approach the Gaussian, their q=2q = 2 member [55, 56], so heavy-tailed transport is generic in disordered and multiscale media.

On a lattice, the coupling between two sites at distance rr is the corresponding coefficient of the centered discretized fractional derivative, Jr,qJ_{r,q}, decaying asymptotically as r−(1+q)r^{-(1+q)} with subleading power-law corrections. The interaction is strongly nonlocal and ferromagnetic for q<2q < 2, reduces to the nearest-neighbor bond at q=2q = 2, and acquires a weak antiferromagnetic tail for q>2q > 2, so that long- and short-range regimes arise as limits of a single tunable model [66, 67]. Quantum Ising chains with pure power-law couplings r−(1+q)r^{-(1+q)} are Gaussian for q<2/3q < 2/3 [68, 69, 70] and, according to functional renormalization-group and quantum Monte Carlo studies, in the short-range class for q>7/4q > 7/4 [69, 71]. The fractional couplings share this tail, but whether the fractional chain follows the same thresholds has not been established; classical simulations of the fractional model are consistent with the corresponding classical thresholds [66]. For q≤1q \le1 the fractional couplings confine domain walls into bound pairs [72, 73]. The critical exponents vary continuously with the fractional order [66, 67], and the spreading of the entanglement follows the Lévy light cones [67]. These features make fractional models a natural setting in which to confront the KZM with a continuous family of exponents, which is also relevant for quantum simulators of realistic materials beyond idealized lattices.

In this work, we study the quantum critical dynamics of the fractional Ising chain with its interaction generated by a fractional derivative of continuously tunable order, by means of time-dependent variational principle (TDVP) simulations [74] with a matrix-product-operator (MPO) and matrix-product-state (MPS) representation of the long-range interacting Hamiltonian and its eigenstates, respectively. Driving the transverse field across the critical point, we obtain the residual kink density as a function of the driving time and find a power-law exponent that continuously varies with the fractional order. We furthermore extract the critical exponents from the equilibrium quantities alone, from the finite-size scaling of the gap, and from the entanglement light cone arising from a local perturbation at criticality. With these exponents, the Kibble-Zurek prediction accounts for the measured scaling at intermediate- and short-range order, while the measured decay is slower at small fractional order. Going beyond the mean kink number, we resolve the higher cumulants and reconstruct the full kink number distribution of a nonintegrable long-range spin chain. These results are benchmarked against the exactly solvable free-fermion approximation of the model, a fractional pp-wave superconductor. The description deviates appreciably at small fractional order, improves steadily above unit order, and becomes quantitatively accurate in the short-range limit.

Within the free-fermion description, we derive the full statistics of both the excitations and the kinks. We show that the kink number relative to the free-fermion ground state coincides with the number of excitations, up to a fractional-order dependent prefactor. We further prove that in any free-fermion state the kink number variance cannot exceed twice its mean and the total correlation of a bond cannot exceed its local variance, implying a Gaussian limiting distribution for the full kink statistics.

In the TDVP simulations, both bounds are violated deep in the long-range regime, also at the center of the chain, where kinks are created close to each other, consistent with the domain-wall confinement induced by the kink-kink interactions. Nevertheless, the kink distribution tion still approaches a Gaussian for large kink numbers. The paper is organized as follows. Section II introduces the fractional Ising chain, the numerical scheme used throughout, and the numerically obtained kink-number cumulants and full counting statistics. Section III then measures zz and ν\nu independently of the driving protocol, through the finite-size gap scaling and the entanglement light cone, and compares the corresponding KZ exponent with the numerical results of the decay of the mean kink number. Section IV closes the argument by developing the free-fermion description, the fractional pp-wave superconductor, from which the critical exponents, the exact Landau-Zener kink statistics, the general free-fermion bounds on the kink cumulants and correlations and the confrontation with the KZM follow analytically, together with the kink-kink correlations, which we compare with the TDVP simulations. All technical details are collected in the appendices.

Fractional Ising model

Model and numerical method

We consider the fractional transverse-field Ising chain

H^Ising(t)=−g(t)∑i=1Lσ^iz−(1−g(t))∑i=1L∑r=1LJr,qσ^ixσ^i+rx(1)\hat{H}_{\mathrm{Ising}}(t) = -g(t)\sum_{i=1}^{L}\hat{\sigma}_{i}^{z} -(1-g(t))\sum_{i=1}^{L}\sum_{r=1}^{L}J_{r,q}\hat{\sigma}_{i}^{x}\hat{\sigma}_{i+r}^{x} \tag*{(1)}

driven by the linear protocol g(t)=1−t/τQg(t)=1-t/\tau_{Q}, t∈[0,τQ]t\in[0,\tau_{Q}], with the driving time τQ\tau_{Q} and open boundary conditions, so that the second sum runs over the bonds with i+r≤Li+r\leq L. We set ℏ=1\hbar=1, so that times are measured in units of the inverse energy scale of Eq. (1). The couplings are given by the coefficients of the centered discretized Riesz fractional derivative of order qq [63], expressed as binomial coefficients of the noninteger argument,

Jr,q=(−1)r+1(qq/2+r).(2)J_{r,q}=(-1)^{r+1}\binom{q}{q/2+r}. \tag*{(2)}

For large separations the couplings decay as

Jr,q≃Γ(q+1)πsin⁡(πq2)r−(1+q),r→∞.(3)J_{r,q}\simeq\frac{\Gamma(q+1)}{\pi}\sin\left(\frac{\pi q}{2}\right)r^{-(1+q)},\qquad r\to\infty. \tag*{(3)}

The next subleading correction scales as r−(3+q)r^{-(3+q)}, so that the profile approaches a power law only asymptotically and retains additional structure at short and intermediate range [67]. For 0<q<20<q<2 all couplings are ferromagnetic and heavy-tailed, describing Lévy-type long-range interactions. At q=2q=2 the binomial terminates after the first bond, J1,2=1J_{1,2}=1, and the standard nearest-neighbor transverse-field Ising model (TFIM) is recovered. For q>2q>2 the tail changes sign while decaying faster than r−3r^{-3}, so that a dominant nearest-neighbor ferromagnetic bond competes with a weak long-range antiferromagnetic background. The equilibrium critical exponents vary smoothly with the fractional order [66].

At g=1g=1 the ground state is the fully polarized paramagnet, while below the critical point the Z2\mathbb{Z}_{2} symmetry σ^ix→−σ^ix\hat{\sigma}_{i}^{x}\to-\hat{\sigma}_{i}^{x} is spontaneously broken, so that the ramp creates kinks between domains of opposite magnetization along xx. At small qq the long-range couplings bind kinks into pairs. At g=0g=0, reversing mm consecutive spins in the bulk of the ordered state creates a kink-antikink pair at the energy cost

V(m)=4∑r≥1Jr,qmin⁡(r,m)=V0+4Aqq(1−q)m1−q+O(m−1−q),(4)\begin{aligned} V(m)=4\sum_{r\geq1}J_{r,q}\min(r,m) \\ &=V_{0}+\frac{4A_{q}}{q(1-q)}m^{1-q}+O(m^{-1-q}), \tag*{(4)} \end{aligned}

for q≠1q\ne1, with Aq=Γ(q+1)sin⁡(πq/2)/πA_{q}=\Gamma(q+1)\sin(\pi q/2)/\pi the tail amplitude of Eq. (3)} and $V_{0}=\frac{q}{q-1}\left(q/2\right)$, which equals $4\sum_{r}rJ_{r,q}$ for $q>1$. For $q<1$ the potential grows as $m^{1-q}$, and logarithmically at $q=1$, confining kinks into pairs [72, 73]. For $1<q<2$ it saturates at $V_{0}$, i.e., the energy cost of two free walls, and for $q>2$ it decreases with $m$, as the antiferromagnetic tail repels the walls at short distance. The free-fermion approximation of {xref}Sec. IV A does not contain this kink-kink interaction {citep}[76]`.

Away from q=2q=2 the model is not integrable, and we study it numerically within the MPS formalism [75] using the open-source package ITensors.jl [77], for L=150L=150 spins. The Hamiltonian is represented as an MPO, built with the OpSum construction of ITensors.jl directly from all terms Jr,qσ^ixσ^i+rxJ_{r,q}\hat{\sigma}_{i}^{x}\hat{\sigma}_{i+r}^{x}, 1≤r≤L−11\leq r\leq L-1, with the exact couplings of Eq. (2) rather than from a fit by a sum of exponentials [78]. The conversion to an MPO compresses, at each bond ll, the coupling matrix JijJ_{ij} with i≤l<ji\leq l<j between the two halves of the chain by a singular value decomposition with a cutoff of 10−1510^{-15} [79], so that the MPO bond dimension at bond ll equals the rank of this matrix plus two. As the couplings form a single smoothly decaying sequence, these matrices have at most 18 singular values above 10−1510^{-15} of the largest one for every qq. The MPO bond dimension is therefore at most 20, compared with L/2+2=77L/2+2=77 for the uncompressed MPO and 12–16 for fits by 10−1410^{-14} exponentials [67], and the couplings are reproduced to a relative accuracy of at least 10−810^{-8}. The transverse-field and interaction parts are stored as separate MPOs and combined at each time step with g(t)g(t) evaluated at the midpoint of the step. The ground states are obtained by the density-matrix renormalization group (DMRG), and the driven dynamics by the two-site TDVP [74] implemented in TimeEvoMPS.jl [80], starting from the paramagnetic product state, with a maximal bond dimension χmax⁡=200\chi_{\max}=200, time steps 0.01≤δt≤0.40.01\leq\delta t\leq0.4 with δt≤τQ/10\delta t\leq\tau_{Q}/10, and truncation cutoffs between 10−710^{-7} and 10−1010^{-10}, which bound the discarded weight of each truncation whenever the bond dimension stays below χmax⁡\chi_{\max}.

To control the truncation, each of the 356 driving times was simulated with typically four to six combinations of δt\delta t and cutoff, 1469 runs in total over 17 fractional orders. With cutoffs of 10−810^{-8} and below, the cumulants, defined in Sec. II B, deviate from those of the most accurate run at the same qq and τQ\tau_Q by a median of 0.04% for κ1\kappa_1 and 0.2% for κ2\kappa_2, and by less than 0.3% and 2% in 90% of the cases, while the deviation of κ3\kappa_3 stays below 6% of κ2\kappa_2 in 90% of the cases. A cutoff of 10−710^{-7} changes κ2\kappa_2 by about 4%, and the figures show the most accurate run at each driving time. The bond dimension reaches χmax⁡\chi_{\max} in 12% of the runs with cutoffs of 10−810^{-8} and below, all at q≤0.9q \leq0.9 apart from a few at q=1.25q = 1.25 and for τQ≳20\tau_Q \gtrsim20. Where saturated and unsaturated runs exist at the same τQ\tau_Q, for example at q=0.2q = 0.2 and τQ=30\tau_Q = 30, their cumulants agree within the deviations given above. For q≲0.3q \lesssim0.3 the ratio κ2/κ1\kappa_2/\kappa_1 exceeds 2 at slow ramps, with κ2/κ1≃3.1\kappa_2/\kappa_1 \simeq3.1–5.1 at q=0.1q = 0.1, 2.2–3.0 at q=0.2q = 0.2 and 2.0–2.6 at q=0.3q = 0.3 for τQ≥50\tau_Q \geq50, so that the violation of the free-fermion bound of Sec. IV is not an effect of the truncation.

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