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Ground-state condensation in the dilute hard-sphere gas

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Abstract

We prove Bose–Einstein condensation in every ground state of a dilute three-dimensional hard-sphere Bose gas. At every sufficiently small fixed gas parameter, the constant orbital contains a positive fraction of the particles in the thermodynamic limit. The fraction can be chosen independently of the gas parameter, and the conclusion holds for arbitrary complex ground states.

Introduction

Bose–Einstein condensation means that a single one-particle state carries a macroscopic part of a many-particle system. For a homogeneous gas the natural candidate is the constant orbital. We prove that this orbital contains a fixed positive fraction of every ground state of a sufficiently dilute three-dimensional hard-sphere Bose gas, in the thermodynamic limit at fixed density and fixed exclusion distance. The conclusion permits complex wave functions and a degenerate ground space.

The result

Let ΛL=(R/LZ)3\Lambda_L=(\mathbb{R}/L\mathbb{Z})^3 be the three-dimensional flat torus, with its Euclidean torus distance dLd_L. For NN particles and exclusion distance a>0a>0, define the open configuration set

ΩN,L,a={X∈ΛLN:dL(xi,xj)>a whenever i<j}.\Omega_{N,L,a}=\{X\in\Lambda_L^N:d_L(x_i,x_j)>a\text{ whenever }i<j\}.

The hard-sphere Hamiltonian is the operator associated with the Dirichlet form

qN,L,a[f]=∑i=1N∫ΩN,L,a∣∇if∣2,f∈H01(ΩN,L,a),q_{N,L,a}[f]=\sum_{i=1}^{N}\int_{\Omega_{N,L,a}}|\nabla_i f|^2,\qquad f\in H_0^1(\Omega_{N,L,a}),

restricted to symmetric functions. Thus its kinetic energy is −∑iΔi-\sum_i \Delta_i, and the wave function vanishes at forbidden configurations. The exclusion distance aa is the scattering length: the exterior zero-energy scattering solution is 1−a/∣x∣1-a/\lvert x\rvert. All wave functions below are extended by zero to ΛLN\Lambda_L^N.

For a normalized bosonic vector Ψ\Psi, its one-particle density matrix and the normalized constant orbital are

ΓΨ(1)(x;y)=N∫ΛLN−1Ψ(x,Y)Ψ(y,Y)‾ dY,φ0,L=L−3/2.\Gamma^{(1)}_\Psi(x;y)=N\int_{\Lambda_L^{N-1}}\Psi(x,Y)\overline{\Psi(y,Y)}\,\mathrm{d}Y,\qquad\varphi_{0,L}=L^{-3/2}.

In particular, Tr⁡ΓΨ(1)=N\operatorname{Tr}\Gamma^{(1)}_\Psi=N. We measure condensation by

B(Ψ)=⟨φ0,L,ΓΨ(1)φ0,L⟩N=1L3∫∣∫Ψ(x,Y) dx∣2dY.(1)B(\Psi)=\frac{\langle\varphi_{0,L},\Gamma^{(1)}_\Psi\varphi_{0,L}\rangle}{N} =\frac{1}{L^3}\int\left|\int\Psi(x,Y)\,\mathrm{d}x\right|^2\mathrm{d}Y. \tag*{(1)}

This quantity lies in [0,1][0,1].

Theorem 1.1 (Condensation in every ground state). There are absolute constants ε0,c0>0\varepsilon_0,c_0>0 with the following property. Fix a,ρ>0a,\rho>0 satisfying ρa3<ε0\rho a^3<\varepsilon_0. For every sequence of particle numbers NkN_k and lengths LkL_k such that

Nk⟶∞,Lk⟶∞,NkLk3⟶ρ,N_k\longrightarrow\infty,\qquad L_k\longrightarrow\infty,\qquad\frac{N_k}{L_k^3}\longrightarrow\rho,

and every choice of normalized, possibly complex, bosonic ground eigenvectors Ψk\Psi_k of the hard-sphere Hamiltonians,

lim inf⁡k→∞B(Ψk)≥c0.\liminf_{k\to\infty}B(\Psi_k)\ge c_0.

The same constant c0c_0 works at all sufficiently small fixed gas parameters ρa3\rho a^3. The volume needed to approach this bound may depend on aa and ρ\rho. We prove a positive fraction; we do not estimate the optimal depletion or show that the fraction tends to one as ρa3\rho a^3 tends to zero.

Corollary 1.2 (Ground-space states). Under the hypotheses of Theorem 1.1, the same lower bound holds for every sequence of density operators supported on the bosonic ground eigenspaces. In particular, it holds for the normalized ground-space projections Πk/Tr⁡Πk\Pi_k/\operatorname{Tr}\Pi_k, and for every sequence of normalized nonnegative ground functions.

Here the one-particle density matrix of a density operator is defined by linearity. The proof below is uniform over its pure ground vectors; convexity then proves the corollary. No choice of a preferred ground vector or a basis of positive ground functions is required.

Context

The ideal-gas prediction grew from Bose’s counting of light quanta and Einstein’s extension to a gas of material particles [8, 13, 14]. For an interacting gas, the density-matrix criterion of Penrose and Onsager [30] identifies condensation through a macroscopic one-particle occupation. Bogoliubov’s theory assumes a macroscopically occupied zero mode to derive the weakly interacting gas’s excitation picture [7]. For hard spheres, Lee, Huang and Yang’s pseudopotential calculation predicts a depleted fraction of order ρa3\sqrt{\rho a^3} [23]. The rigorous occupation problem is to justify macroscopic condensation itself before seeking this sharper depletion law.

The hard-sphere energy theory runs from Dyson’s bounds [12] and the leading dilute asymptotics of Lieb and Yngvason [26] to the sharp Lee–Huang–Yang lower bound of Fournais and Solovej, which includes hard cores [17]. Basti, Brooks, Cenatiempo, Olgiati and Schlein proved the matching upper coefficient for hard spheres and subsequently for a class of general nonnegative potentials [3, 4]. These energy asymptotics do not determine single-orbital occupation as the one-particle spectral gap vanishes in large volume. Lieb and Yngvason explicitly separated that question from their energy theorem [26].

Continuum condensation results allowing scaled hard cores include the trapped Gross–Pitaevskii theorem of Lieb and Seiringer [25] and the homogeneous canonical positive-temperature theorem of Deuchert and Seiringer [11]. Low-energy results of Fournais and of Chong, Liang and Nam [10, 16], and Junge’s canonical low-temperature result in Neumann boxes [22] Corollary 6, treat joint dilute and increasing-volume limits. These regimes permit the gas parameter to decrease as the volume grows. Here aa and a positive ρ\rho are fixed before the volume grows without restriction, and the lower fraction is uniform over all ground vectors.

Sütő’s thermodynamic condensation theorem, above a temperature-dependent density threshold, assumes nonnegative potentials with nonnegative Fourier transform and additional regularity and integrability [33] Theorem 1.2; these hypotheses exclude a literal hard core. Galanda and Pinamonti construct algebraic equilibrium states for smooth interactions, using coupled cutoff-removal and weak-interaction limits in one setting and Gross–Pitaevskii scaling in another [19, 20]. Their state formulations and limit orders differ from the present hard-sphere problem. Solovej’s 2025 survey identifies fixed-density ground-state condensation as a major open problem [32] Section 5. Theorem 1.1 establishes a positive lower limiting occupation fraction for sufficiently dilute three-dimensional hard spheres, with the fixed-parameter order of limits in Equation (1.2).

The path method has separate antecedents. Benjamini, Pemantle and Peres constructed unpredictable paths with controlled intersections [5] Theorem 1.3 and Lemma 3.1. Abbe, Massoulié, Montanari, Sly and Srivastava averaged noisy group differences along paths joining prescribed endpoints [1]; Garban and Spencer adapted this averaging method to symmetry breaking in classical disordered spin systems [21]. Averaging path likelihoods before taking their second moments also underlies trail detection [2, 6] and the point-reassignment argument of Peres and Sly [31], Proposition 2.1. Our exterior-shell detours use Kesten’s boundary-connectivity theorem in Timár’s formulation [34], arXiv version 2, Theorem 4.

Our sole companion input is the explicit random lattice skeleton and both encounter moments in A density-uniform condensate bound for dilute Bose gases [29], Section 8.1, pp. 22–24; Lemma 8.1 and Equations (24)–(25), p. 23]. These statements contain no physical parameters. The hard-core energy bounds, obstacle adaptation, conditional-normalizer calculation and phase argument are proved here.

How the proof works

Write Φ=∣Ψ∣\Phi=|\Psi|. The modulus is again a ground function, and we first seek a lower bound for B(Φ)B(\Phi). Expanding the occupation formula gives

B(Φ)=1L3∫Φ(x,Y)Φ(y,Y) dx dy dY.B(\Phi)=\frac{1}{L^3}\int\Phi(x,Y)\Phi(y,Y)\,dx\,dy\,dY.

The same bath YY occurs at the two tagged positions xx and yy. After partitioning the box into cells, we will obtain a uniformly positive contribution to this formula from a fixed positive fraction of ordered cell pairs whose separation is comparable to the box size. A separate phase estimate will then recover B(Ψ)B(\Psi).

Local trajectory changes provide the comparisons between neighboring cells. Multiplying their costs along a long route would lose a factor at every step. Instead we average changes over random routes and bound the second moment of the averaged likelihood. Exact cancellation will leave a cost determined by mutual encounters of two routes, with a bound independent of their lengths.

Local trajectories and the exposed environment. Change length units so that each unit cell contains on average DD particles and the exclusion distance is r=α/Dr = \alpha/D, with α\alpha in a fixed interval. Dilution then corresponds to large DD; (6) records the invariant gas parameter. Local kinetic inequalities and normalized particle insertion show that cells with too few particles or too many close neighbors have small joint probabilities. An exact stationary killed-Brownian law, whose position marginal is Φ2\Phi^2, turns these estimates into a supply of short trajectories that can be replaced through a home cell or a face-neighbor cell.

At each cell we allocate the movable labels to many disjoint groups. For one group at a time, expose the outer endpoints and all trajectories outside the group. A cell is usable when enough of its remaining labels admit successful replacements against these frozen trajectories. The unexposed law is a product of bridge laws that already impose individual oscillation and confinement cutoffs and avoidance of the frozen paths, conditioned further on mutual hard avoidance. This exact conditional law, and an unconditional joint bound on unusable cells, are the two outputs of Section 6. We keep the two probability statements separate throughout the comparison.

Distant cells and a common bath. For each required pair of distant cells, the joint obstacle bounds retain a set of exposed environments of fixed positive probability. On this set, draw a random lattice route from the companion’s skeleton law and reroute it around encountered finite unusable clusters along their good exterior shells. The resulting route uses nearest-neighbor steps, so every step admits the local replacements. Averaging the retained distribution of environments, with two independent route choices drawn in each common environment, gives a bounded exponential moment for their mutual encounters. One imported estimate controls encounters of the nominal skeletons; the other controls the additional encounters caused by detours, after the local obstacle probabilities have been summed.

Along a route, choose one group label from each departure cell. Construct two copies of the selected trajectories, preserving each label’s two outer endpoints. Its midpoint lies in its departure cell in the first copy and in the next cell in the second. At every intermediate cell the two different labels share one midpoint. Removing the initial tag from the first copy and the terminal tag from the second leaves the same bath of N−1N - 1 midpoints; Figure 1 depicts these assignments. This produces a common finite measure for two position measures that place a tagged particle in the respective endpoint cells and retain the same observed bath. Their square-root overlap contributes to B(Φ)B(\Phi) through the exact cell-average identity in (68).

The two midpoint assignments

Figure 1. The two midpoint assignments. Each departure label moves one cell along the path in the second copy; the drawing suppresses the intermediate cells before UdU_d. Removing the highlighted tags leaves the same bath midpoints. Each vertical column is one proposal factor, with a common midpoint and one path in each copy when both are required.

To lower-bound this overlap, average the change of measure over routes and label choices, and bound its second moment. The interaction normalizers are retained exactly. In the product of two likelihoods, the normalizers from portions of the routes far from one another cancel; only nearby encounters and shared labels contribute a cost. The preceding encounter moment controls that cost uniformly in the endpoint separation. Section 8 constructs the two-copy measure before proving and applying this cancellation. Finally, summing the overlap contributions of a number of disjoint groups proportional to DD compensates for the normalization of one tagged particle and yields a fixed lower bound for B(Φ)B(\Phi).

Recovering the phases. Equality of the kinetic energies of Ψ\Psi and Φ\Phi forces a constant phase on each connected component of the allowed configuration set. Those phases may differ between components. Fix the bath and cover its forbidden balls by small closed cubes, filling the bounded holes of each connected cluster. The points left outside the filled regions communicate through the open allowed one-particle slice and hence share one phase. Small clusters have little total filled volume. A large cluster would force many nearby particles with close partners, an event controlled by the joint spatial estimates. If δgeom\delta_{\mathrm{geom}} is the discarded volume fraction averaged under the ground-state bath marginal, the elementary estimate

B(Ψ)≥B(Φ)−4δgeomB(\Psi) \ge B(\Phi) - 4\sqrt{\delta_{\mathrm{geom}}}

transfers the modulus bound to the original vector. We first fix the positive modulus fraction and only then strengthen the dilution threshold to make this phase loss smaller.

Section 2 gives the form and phase facts. Sections 3–5 supply the spatial, path and bridge estimates for the local replacements. Section 6 organizes the groups and their conditional law, Section 7 constructs the routes, and Section 8 proves the modulus bound. Section 9 controls the filled regions. Section 10 fixes the constants and returns to arbitrary thermodynamic sequences in the original units.

Ground states and phase transfer

The probabilistic part of the proof uses the squared modulus of a ground state. This section justifies that reduction and identifies the additional estimate needed to recover the occupation of an arbitrary complex state. The relevant phase information is local: moving one particle with the bath fixed preserves its phase whenever the motion stays in the allowed region.

Length units and the occupation fraction

We work on the scaled torus ΛK=(R/KZ)3\Lambda_K = (\mathbb{R}/K\mathbb{Z})^3, with integer side KK, volume V=K3V = K^3, and exclusion distance r>0r > 0. Its distance is denoted by dd. For every integer n≥0n \ge0 put

Ωn={(x1,…,xn)∈ΛKn:d(xi,xj)>r for i<j},\Omega_n = \{(x_1,\ldots,x_n) \in\Lambda_K^n : d(x_i,x_j) > r\ \text{for } i < j\},

with Ω0\Omega_0 a single point. The full, labelled-particle Dirichlet form, without a symmetry restriction, is

qn[f]=∑i=1n∫Ωn∣∇if∣2,D(qn)=H01(Ωn).q_n[f] = \sum_{i=1}^{n} \int_{\Omega_n} |\nabla_i f|^2,\qquad D(q_n) = H_0^1(\Omega_n).

Here H01H_0^1 is the closure of smooth functions compactly supported in the open configuration set. The bosonic form is its restriction to functions invariant under coordinate permutations. Write EnE_n for the full bottom energy when Ωn\Omega_n is nonempty, set En=+∞E_n = +\infty otherwise, and put E0=0E_0 = 0. We consider nonempty ΩN\Omega_N. The particle-insertion argument in the next section proves nonemptiness for every additional particle number at which an energy is used. Every wave function is extended by zero outside its allowed set.

The mean particle count per unit cell and its product with the exclusion distance are

D=NK3,α=Dr,α02≤α≤2α0,D≥D0.D = \frac{N}{K^3},\qquad\alpha= Dr,\qquad\frac{\alpha_0}{2} \le\alpha\le2\alpha_0,\qquad D \ge D_0.

The numerical constant α0\alpha_0 will be fixed sufficiently large, and D0D_0 will subsequently be increased. Partition the torus into unit cells Bv=v+[−1/2,1/2)3B_v = v + [-1/2,1/2)^3, indexed by L=(Z/KZ)3\mathcal{L} = (\mathbb{Z}/K\mathbb{Z})^3; these sets are understood modulo KK. All estimates are uniform in the ground state and in the displayed α\alpha window. A constant may depend on parameters already fixed, but not on NN or KK. Volume thresholds may depend on the fixed density; where needed, they will be uniform when DD ranges over a compact subinterval of [D0,∞)[D_0,\infty).

To relate these units to the original torus of side LL and exclusion aa, choose a length unit s=L/Ks=L/K and set r=a/sr=a/s. The map

Ψ~(z1,…,zN)=s3N/2Ψ(sz1,…,szN)\widetilde{\Psi}(z_1,\ldots,z_N)=s^{3N/2}\Psi(sz_1,\ldots,sz_N)

is unitary and multiplies the quadratic form by s2s^2. It therefore preserves ground states. The gas parameter is unchanged:

Dr3=NL3a3=a3D2.(2)Dr^3=\frac{N}{L^3}a^3=\frac{a^3}{D^2}. \tag*{(2)}

Thus, with α\alpha in its fixed window, increasing the particle count DD per unit cell corresponds to increasing physical dilution. The integer KK will be chosen at the end of the proof.

Let Ψ\Psi be a normalized, possibly complex, bosonic ground state on ΛK\Lambda_K. Write Y=(x2,…,xN)Y=(x_2,\ldots,x_N) and define

ΓΨ(1)(x;y)=N∫Ψ(x,Y)Ψ(y,Y)‾ dY,φ0(x)=V−1/2.\Gamma_{\Psi}^{(1)}(x;y)=N\int\Psi(x,Y)\overline{\Psi(y,Y)}\,\mathrm{d}Y,\qquad\varphi_0(x)=V^{-1/2}.

The operator with kernel Ψ(x,Y)\Psi(x,Y) is Hilbert–Schmidt with squared norm one, so ΓΨ(1)\Gamma_{\Psi}^{(1)} is positive, trace class, and has trace NN. Consequently the normalized constant-orbital occupation is

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